- 1 - High efficiency arrays of polymer solar cells fabricated by spray - coating in air
نویسندگان
چکیده
We present bulk heterojunction organic solar cells fabricated by spray-casting both the PEDOT:PSS hole-transport layer (HTL) and active PBDTTT-EFT:PC71BM layers in air. Devices were fabricated in a (6 x 6) array across a large-area substrate (25 cm) with each pixel having an active area of 6.45mm. We show that the film uniformity and operational homogeneity of the devices are excellent. The champion device with spray cast active layer on spin cast PEDOT:PSS had an power conversion efficiency (PCE) of 8.75%, and the best device with spray cast active layer and PEDOT:PSS had a PCE of 8.06%. The impacts of air and light exposure of the active layer on device performance are investigated and found to be detrimental.
منابع مشابه
Fully spray-coated ITO-free organic solar cells for low-cost power generation
We report on cost-effective ITO-free organic solar cells (OSCs) fabricated by a spray deposition method. All solution-processable layers of solar cells—a highly conductive poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) layer and a photoactive layer based on poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 (PCBM)—were spray-coated. PEDOT:PSS a...
متن کاملSpray-coated nanoscale conductive patterns based on in situ sintered silver nanoparticle inks
Nanoscale patterns with high conductivity based on silver nanoparticle inks were fabricated using spray coating method. Through optimizing the solution content and spray operation, accurate nanoscale patterns consisting of silver nanoparticles with a square resistance lower than 1 Ω /cm2 were obtained. By incorporating in situ sintering to substitute the general post sintering process, the time...
متن کاملOptimization of Annealing Process for Totally Printable High-current Superstrate CuInS2 Thin-Film Solar Cells
Planar superstrate CuInS2 (CIS) solar cell devices are fabricated using totally solution-processed deposition methods. A titanium dioxide blocking layer and an In2S3 buffer layer are deposited by the spray pyrolysis method. A CIS2 absorber layer is deposited by the spin coating method using CIS ink prepared by a 1-butylamine solvent-based solution at room temperature. To obtain optimum annealin...
متن کاملMulti-source/component spray coating for polymer solar cells.
A multi-source/component spray coating process to fabricate the photoactive layers in polymer solar cells is demonstrated. Well-defined domains consisting of polymer:fullerene heterojunctions are constructed in ambient conditions using an alternating spray deposition method. This approach preserves the integrity of the layer morphology while forming an interpenetrating donor (D)/acceptor (A) ne...
متن کاملFabrication of Annealing-Free High Efficiency and Large Area Polymer Solar Cells by Roller Painting Process
The polymer solar cells were fabricated by a novel solution coating process, the roller painting. The roller painted film composed of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) has smoother surface than the spin coated film. Since the roller painting is accompanied with shear and normal stresses and is also a s low drying process, the process induces eff...
متن کامل